(N-Benzoyl-N′-phenylthiourea-κS)chlorido(η4-1,5-cyclooctadiene)rhodium(I)
نویسندگان
چکیده
The title compound, [RhCl(C(8)H(12))(C(14)H(12)N(2)OS)], is a rhodium(I) derivative with a functionalized thio-urea ligand. Despite the presence of several heteroatoms, the thio-urea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approximately square planar about the Rh(I) atom, with two bonds to the π-electrons of the 1,5-cyclo-octa-diene ligand, one bond to the Cl(-) ligand and one bond to the S atom of the thio-urea ligand. The mol-ecular structure is stabilized by intra-molecular N-H⋯O and N-H⋯Cl hydrogen bonding. Inter-molecular N-H⋯O hydrogen-bonding inter-actions lead to the formation of layers extending parallel to (011).
منابع مشابه
(N-Benzoyl-N′,N′-diphenylthioureato-κ2 S,O)(η4-cycloocta-1,5-diene)rhodium(I)
The title complex, [Rh(C(20)H(15)N(2)OS)(C(8)H(12))], exhibits an essentially square-planar coordination environment around the Rh(I) atom, which bears a bidentate cyclo-octa-diene ligand as well as a monoanionic bidentate benzoyl-thio-ureate ligand. The Rh(I) atom, the S- and O-donor atoms and the alkene centroids of the cyclo-octa-diene ligand do not deviate by more than 0.031 Å from their le...
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